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Journal of Structural Chemistry

2008 year, number 2

MOLECULAR STRUCTURE OF 1-PHENYL-1-FLUORO-5-METHYLQUASISILATRANE (2-PHENYL-2-FLUORO-1,3-DIOXA-6-AZA-6-METHYL-2-SILACYCLOOCTANE)

M. G. Voronkov, А. А. Korlyukov, Г‰. А. Zelbst, Е. А. Grebneva, О. М. Trofimova, М. Y. Antipin
Keywords: 1-phenyl-1-fluoro-5-methylquasisilatrane, molecular structure, X-ray analysis
Pages: 390-393

Abstract

The crystal and molecular structure of 1-phenyl-1-fluoro-5-methylquasisilatrane PhFSi(OCH2CH2)2NMe was investigated by X-ray diffraction at 100 K. The coordination polyhedron of the silicon atom in the molecule is a slightly distorted trigonal bipyramid containing fluorine and nitrogen atoms in the axial positions and two endocyclic oxygen atoms and the carbon atom of the phenyl group at three vertices of the equatorial plane.