STRUCTURAL AND THERMODYNAMIC PARAMETERS AND INTERMOLECULAR INTERACTIONS IN AQUEOUS FORMIC ACID AMIDES
A. M. Zaichikov, М. А. Krest'yaninov
Keywords: internal pressure, intermolecular interactions, structure of aqueous solutions, formamides
Pages: 299-308
Abstract
The structural and thermodynamic characteristics of aqueous solutions of formamide, N-methylformamide, N,N-dimethylformamide, and N,N-diethylformamide were calculated. The specific and nonspecific components of the total energy of intermolecular interactions were determined. The limits of the concentration regions with differently arranged structures of solutions were established, and the preferable solvation parameters of the solution components were evaluated.
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