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Chemistry for Sustainable Development

2009 year, number 1

Comparison of the efficiency of oxidation of sulphureous compounds of the diesel fraction by various oxidants in a two-stage process of sulphur removal (a combination of oxidation and adsorption)

E. B. Krivtsov, A. K. Golovko
Keywords: diesel fuel, oxidative sulphur removal
Pages: 89-95

Abstract

Comparative analysis of the efficiency of oxidation of sulphureous compounds of diesel fraction by various oxidants (ozone, peroxides) in a two-stage process of sulphur removal (a combination of oxidation and adsorption) was carried out. The dependence of the oxidation degree of sulphurous compounds of the diesel fraction on the amount of the oxidant used and on the process conditions were investigated. The changes in the group composition of saturated and aromatic hydrocarbons, sulphureous compounds of the saturated and aromatic character under the oxidation of the sample followed by adsorption purification of the resulting products were analyzed.