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Chemistry for Sustainable Development

2006 year, number 4

Synthesis and Application of Fluorine-Containing Ethers Based on Perfluoroolefins

G. G. FURIN
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 9, Novosibirsk 630090 (Russia)
E-mail: furin@nioch.nsc.ru
Pages: 303-318

Abstract

Methods of synthesis of fluorine-containing dialkyl and fatty-aromatic ethers involving the reactions of aliphatic alcohols and phenols, including aromatic ones, with perfluoroolefins are considered. To obtain various fluorine-containing polyethers, polyhydric alcohols were used in reactions with perfluorinated tri-, tetrafluoroethylene and hexafluoropropylene. Some properties of fluorine-containing ethers are discussed; examples are their application are presented.