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Chemistry for Sustainable Development

2005 year, number 5

On the Possible Use of Dicarbon Fluoride Intercalates as Containers for Volatile Substances

V. G. MAKOTCHENKO and A. S. NAZAROV
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 3, Novosibirsk 630090 (Russia) E-mail: mwg@che.nsk.su
Pages: 619-625

Abstract

A possibility has been shown to create molecular chemical containers for the storage, the transportation and release in the environment of gaseous and liquid, chemically and physiologically active materials on the basis of a matrix of dicarbon fluoride. As regards a set of operational parameters such as the versatility in respect to the introduced material (i.e. capacity to form compounds with various classes of inorganic and organic matters), the thermal (up to 390oC) and hydrolytic stability, capacity (up to 30 mass %), the protection degree of the introduced material against the influence of external factors and the storage period (for years), the new molecular chemical containers on the basis of dicarbon fluoride outperform the containers on the basis of alternative familiar types of inclusion compounds.