Mechanochemical Conversion of Gaseous Oil Hydrocarbons in the Systems Gas-Solid
O. E. GAMOLIN1, A. K. GOLOVKO1, O. I. LOMOVSKIY2, V. F. KAMYANOV1 and S. G. MAMYLOV1
1Institute of Petroleum Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademicheskiy 3, Tomsk 634021 (Russia) E-mail: golovko@ipc.tsc.ru
2Institute of Solid State Chemistry and Mechanochemistry,
Siberian Branch of the Russian Academy of Sciences,
Ul. Kutateladze 18, Novosibirsk 630128 (Russia) E-mail: lomov@solid.nsc.ru
Pages: 165-172
Abstract
The effect of mechanical treatment on complex systems containing a solid phase and the components of casing-head gas is considered. The process is carried out in planetary ball mills with the acceleration of milling bodies (steel balls) up to 600 m/s2. An intense mechanical action on the material of balls and mill walls causes the formation of active centres initiating transformations of the gaseous components. The possibility to obtain hydrogen and methane from hydrocarbon gases by means of mechanochemically initiated destruction was demonstrated. The presence of a solid phase, i.e. crystal quartz, which efficiently generates active centres of radical nature during mechanical treatment, increases the transformation degree of initial components.
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