Synthesis of Bismuth (III) Stearates
KLAVDIY G. MYAKISHEV and VLADIMIR V. VOLKOV
Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 3, Novosibirsk 630090 (Russia)
Pages: 379-385
Abstract
Reactions of CdX (X = Br, I) with MBH4 (M = Li, Na, K) under mechanical activation (MA) of the mixtures of crystalline compounds in vacuum vibratory mill are investigated. It is discovered that the reactions are accompanied by the formation of B2H6; its yield depends on the nature of CdX2, MBH4and correlates with the calculated values. It is shown that the mechanochemical synthesis of B2H6 depends on temperature within the range 50_120
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