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Chemistry for Sustainable Development

2002 year, number 3

Liquid - Vapour Equilibrium at HCl Recovery from Mixtures with Chlorosilanes

LIDIA A. BORISOVA, MIKHAIL F. REZNICHENKO, PETR P. SEMYANNIKOV and ANATOLY M. ORLOV
Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences,
Pr. Lavrentyeva 3, Novosibirsk 630090 (Russia) E-mail: phys@che.nsk.su
Pages: 281-284

Abstract

The liquid - vapour equilibrium is investigated and phase diagrams liquid - vapour are composed for the systems: HCl - SiCl4 and HCl - SiHCl3 within temperature range 203-293 K at total pressure Ptotal = 1.3 atm. The data obtained can be used to choose conditions of HCl desorption from the solutions HCl with chlorosilanes in order to recover HCl from these mixtures.