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Chemistry for Sustainable Development

2002 year, number 1-2

Effect of Mechanical Treatment on the Structure of Barium Peroxide

ISMAIL A. MASSALIMOV1 and ASKAR R. KILMAMETOV2
1Institute of Mechanics, Ufa Scientific Centre of the Russian Academy of Sciences,
Ul. K. Marxa 12, Ufa 450000 (Russia), E- mail: ismail@bashnet.ru
2Institute of Physics and Advanced Materials, USATU, Ul. K. Marxa 12, Ufa 450000 (Russia)
Pages: 123-128

Abstract

The result of structural investigation of BaO2 powder samples exposed to intensive mechanical treatment in the disintegrator are presented. X-ray patterns of the powders under study displayed features involving significant broadening and changes in positions of X-ray peaks at the certain stage of treatment. The structural instability which manifested in discontinuous jump of lattice parameters, is observed. Assumptions of the reasons causing a sharp leap of lattice parameters and broadening of X-ray lines have been made. Correlation between structural instability and solubility of BaO2 has been established.