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Chemistry for Sustainable Development

2002 year, number 1-2

Structural Changes of ZnO - Cr2O3 System during Mechanical Activation and Their Influence on the Spinel Synthesis

ZORICA V. MARINKOVIC1, TATJANA V. SRECKOVIC1, IREANA PETROVIC-PRELEVIC2 and MOMCILO M. RISTIC3
1Center for Multidisciplinary Studies, University of Belgrade,
Kneza Viseslava 1a, Belgrade 11000
2Faculty of Mining and Geology, University of Belgrade,
Kneza Viseslava 1a, Belgrade 11000
3Serbian Academy of Sciences and Arts,
Kneza Viseslava 1a, Belgrade 11000
E-mail: mzorica@mi.sanu.ac.yu,Yugoslavia
Pages: 113-118

Abstract

An equimolar ZnO and Cr2O3 powder mixture was mechanically activated by grinding using a high-energy vibrational mill for 0-180 min. Structural changes of the material that occur during mechanical treatment were analyzed using the surface characterization method (specific surface area, and based on the latter the calculated mean particle size) and X-ray diffraction line broadening theory. The characteristic temperatures within in the temperature range of 20-1100