Application of Mechanochemistry in Hydrometallation Reactions
ANTON I. LUKASHEVICH, VICTOR V. MOLCHANOV, VASILY V. GOIDIN, GENRIKH A. TOLSTIKOV and ROMAN A. BUYANOV
G. K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences,
Pr. Akademika Lavrentyeva 5, Novosibirsk 630090 (Russia), E-mail: toshik@yandex.ru
Pages: 109-112
Abstract
The mechanochemical method of active aluminium preparation was developed. Also technique of preparation of aluminiumorganic derivatives from unsaturated hydrocarbons is fulfielled. Possibility of realization of hydroalumination under the conditions of mechanochemical activation in drums of planetary mills was demonstrated for the first time. Butillithium via reaction of a butenes mixture with a lithium hydride in conditions of a mechanochemical activation was synthesized.
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