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Thermophysics and Aeromechanics

2026 year, number 4

Density and thermal expansion of liquid rubidium-lead alloys

R.A. Khayrulin, R.N. Abdullaev, S.V. Stankus, A.Sh. Agazhanov
Kutateladze Institute of Thermophysics, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: density, rubidium-lead system, melt, gamma-ray method

Abstract

The density of liquid rubidium-lead alloys containing 40, 45, 55, and 60 at. % Pb was measured for the first time using the gamma-ray attenuation method (transmission of a narrow gamma-ray beam through the sample) in the temperature range from the liquidus to ~1000 K. Based on the obtained results and data for the Rb50Pb50 melt previously investigated by the authors, the concentration dependencies of the molar volume, relative excess molar volume, and volumetric thermal expansion coefficient were determined for the liquid Rb-Pb system. These dependencies deviate significantly from those characteristic of ideal solutions, confirming a tendency toward the formation of chemical short-range order in the liquid state.