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Chemistry for Sustainable Development

2025 year, number 4

Microtubular solid oxide fuel cells with magnetron-sputtered electrolyte

M. O. KHOKHLOVA1,2, A. V. SHIPILOVA2, E. V. SHUBNIKOVA1,2, E. S. TROPIN1, O. A. BRAGINA1, E. A. SMOLYANSKIY3, A. A. SOLOVYEV2, A. P. NEMUDRY1
1Institute of Solid State Chemistry and Mechanochemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2Institute of High Current Electronics, Siberian Branch of the Russian Academy of Sciences, Tomsk, Russia
3National Research Tomsk Polytechnic University, Tomsk, Russia
Keywords: magnetron sputtering, solid oxide fuel cells

Abstract

A bilayer Zr0.85Y0.15O2-δ /Ce0.9Gd0.1O2-δ (YSZ/GDC) solid oxide fuel cell electrolyte was first formed on a microtubular NiO/YSZ anode by the reactive magnetron sputtering method. The composite material La2NiO4+δ -Ce0.8Sm0.2O2-δ (LNO-SDC) was used as the cathode and characterised using the X-ray diffraction method. The current-voltage characteristics of a microtubular solid oxide fuel cell (MT SOFC) with anode-supporting design featuring a two-layer thin-film YSZ/GDC electrolyte and an air LNO-SDC electrode were measured. The microstructure of a single fuel cell after electrochemical measurements was investigated using scanning electron microscopy (SEM). A comparison with literature data on MT SOFCs that have similar functional layers was made.