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Combustion, Explosion and Shock Waves

2025 year, number 4

Evaluation of the Energetic Potential of Nitrohydrazine as a Component of Gunpowder. I. Two-Component Compositions

A. M. Astakhov1, D. B. Lempert2
1Reshetnev Siberian State University of Science and Technology, Krasnoyarsk, Russia
2Federal Research Center for Problems of Chemical Physics and Medical Chemistry, Russian Academy of Sciences, Chernogolovka, Russia
Keywords: nitrohydrazine, ammonium dinitramide, mixed powder, powder force, powder potential, initial projectile velocity, muzzle energy of the projectile, ballistic efficiency of the shot

Abstract

The energy capabilities of a hypothetical zwitterionic nitrohydrazine H3N+N-NO2 as a component of artillery propellants are assessed. Compositions with a hydrocarbon binder, compared to standard propellant charges, allow increasing the muzzle energy of a projectile by ≈33% for a 152-mm howitzer and by ≈27% for a 125-mm tank gun without increasing the temperature of the propellant gases. For a 120-mm mortar, the increase in the muzzle energy of a mine is ≈14%. Similar compositions based on ammonium dinitramide are considered for comparison, which have shown lower efficiency. Compositions with an active binder also achieve high performance indicators. However, they have a high temperature of combustion products, which is unacceptable for most barrel systems.