Substitution of fluorine in potassium pentafluorophenyltrifluoroborate by S-nucleophiles
N. YU. ADONIN1, V. V. BARDIN2
1Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2Vorozhtzov Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Science, Novosibirsk, Russia
Keywords: potassium pentafluorophenyltrifluoroborate, nucleophilic substitution, thiophenol, propanethiol
Abstract
Developing the approach to the synthesis of polyfluorinated boron derivatives formulated as one precursor, a series of target products, tested previously using O-, N-, and C-nucleophiles, a series of potassium 4-arylthiotetrafluorophenyltrifluoroborates was obtained through the action of organylthiols in the presence of bases on potassium pentafluorophenyltrifluoroborate.
|
