Influence of the Elemental Composition of Explosives on the Yield of Detonation Nanodiamonds
V. Yu. Dolmatov1, A. N. Ozerin2, E. D. Eidelman3, A. S. Kozlov1
a:2:{s:4:"TEXT";s:309:"1Special Design and Technological Bureau «Technolog», Saint-Petersburg, Russia
2Enikolopov Institute of Synthetic Polymer Materials, Russian Academy of Sciences, Moscow, Russia
3Saint-Petersburg State Chemical and Pharmaceutical University, Saint-Petersburg, Russia";s:4:"TYPE";s:4:"html";}
Keywords: detonation nanodiamonds, diamond charge mixture, yield of nanodiamonds, elemental composition of explosives
Abstract
A simple method of predictive estimation of the yield of detonation nanodiamonds is described, which takes into account the mass fractions of elements in the carbon-containing explosive with a general formula CaHbNcOd . An empirical dependence of the content of detonation nanodiamonds in the semi-product of nanodiamond synthesis (diamond charge mixture) on the fraction of carbon in molecules of explosives is derived. The yield of detonation nanodiamonds is presented as a function of the fractions of chemical elements in the initial system, which makes it possible to give quantitative predictions of the yield of detonation nanodiamonds.
|
