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Chemistry for Sustainable Development

2024 year, number 4

Terpene Based Amino Oximes on Solid Supports as Selective Extractants of Precious Metals

D. V. ZUBRICHEVA, S. N. BIZYAEV, S. YU. PETRAKOVA, V. D. TIKHOVA, A. V. TKACHEV
Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
Keywords: terpenes, selective extraction, precious metals, nonpolar sorbents, atomic emission spectrometry

Abstract

Chelators based on terpene bis(α-amine oximes) applied onto low-polar sorbents (coal, Sibunit, Polysorb) are effective selective extractants for the extraction of palladium and gold from acidic aqueous solutions containing the mixtures of precious metals and 3 d-elements. The use of sorbents impregnated with the new chelators allows extraction in the liquid-solid mode without using any organic solvent.