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Combustion, Explosion and Shock Waves

2024 year, number 3

Energy Potential of Zwitterionic Nitrohydrazine as a Component of Solid Composite Propellants

A. M. Astakhov1, D. B. Lempert2
1Reshetnev Siberian State University of Science and Technology, Krasnoyarsk, Russia
2Federal Research Center for Problems of Chemical Physics and Medical Chemistry, Russian Academy of Sciences, Chernogolovka, Russia
Keywords: nitrohydrazine, ammonium dinitramide, solid composite propellant, specific impulse, effective impulse, combustion temperature, two-phase impulse loss

Abstract

The energy capabilities of a hypothetical zwitterionic nitrohydrazine H3N+N-NO2 as a component of solid composite propellants are estimated. Two-component compositions with a hydrocarbon or active binder and three-component compositions with the addition of aluminum or aluminum hydride are considered. Compositions with an active binder and aluminum hydride show the highest calculated ballistic efficiency. Their specific impulse exceeds 280 s, and with allowance for two-phase losses, the maximum effective impulse of the third stage rocket motor, it reaches 265.4 s, whereas for an optimized similar composition based on ammonium dinitramide, this value is significantly lower (262.5 s).