Effect of Ultrasonic Treatment on Structural Properties and Colloidal State of Sylvinite Flotation Collector
V. E. Burov, V. Z. Poilov, I. S. Potapov, K. G. Kuz’minykh
Perm National Research Polytechnic University, Perm, Russia
Keywords: Collector, amine hydrochloride, sylvinite flotation, ultrasound effects, dynamic viscosity, Gibbs free energy of activation, coagulation, micelle structure
Abstract
The authors investigate the structural and colloid properties of a collector represented by amine hydrochlorite treated by ultrasound and included in sylvinite flotation. Using the viscosity-temperature dependences, the Gibbs free energy is calculated for amine hydrochlorite with and without treatment by ultrasound. It is found that ultrasound-treated amine added in salt-fat solutions are more stable to coagulation. From the synchronous thermal analysis, IR spectroscopy and H-ray phase analysis, it is inferred that ultrasonic treatment of amine hydrochlorite slightly increases crystallinity of amine. The research findings improve understanding of the ultrasound effect on the change in the structural and colloid properties of the collector, which are important to optimizing output, sustainability and efficiency of potassium chloride production by flotation.
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