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Combustion, Explosion and Shock Waves

2023 year, number 5

TRANSFORMATION OF COPPER AND ZINC COMPOUNDS IN A FLAMELESS COMBUSTION WAVE OF RDX

Yu. M. Mikhailov1, V. V. Aleshin1, L. V. Zhemchugova1, V. S. Smirnov1, D. Yu. Kovalev2
1Federal Research Center for Problems of Chemical Physics and Medical Chemistry, Russian Academy of Sciences, Chernogolovka, Russia
2Merzhanov Institute of Structural Macrokinetics and Problems of Materials Science, Russian Academy of Sciences, Chernogolovka, Russia
Keywords: flameless combustion, RDX, precursor, copper, zinc oxide, nanosized particles

Abstract

The possibility of using the method of flameless combustion of RDX in ballasted systems to produce composite materials containing copper and zinc particles. The initial energetic material was RDX, the binder was hexamethylene diisocyanate, and precursors were copper hydroxocarbonate and copper oxalate. Highly porous composite materials containing nanosized particles of copper, zinc oxide or mixtures thereof were obtained by optimization of the flameless combustion conditions.