Effect of the Pressure of a Gas Mixture on the Ignition, combustion, and Spontaneous Extinction of Cokes of Coals of Different Polymorphisms
V. V. Kalinchak, A. S. Chernenko
Mechnikov Odessa National University, Odessa, 65082 Ukraine
Keywords: particle, coke, pressure, combustion, ignition, ignition
Abstract
The dependence of the diameter of a porous carbon particle on stationary temperature at various pressures of the gas mixture is analyzed. Cases of self-ignition of a particle in a heated nitrogen-oxygen mixture and forced ignition in a cold nitrogen-oxygen mixture leading to quasi-stationary combustion, followed by spontaneous extinction, are considered. It is shown that the combustion temperature of small particles with a diameter d < 200 m, which are characterized by a transient regime of chemical reactions, increases with increasing pressure of the gas mixture. An analytical dependence that qualitatively describes this dynamics is obtained. The greatest growth falls on a pressure interval of 0.1 ÷ 0.3 MPa. A similar analysis for particles of various coals is presented. The dependence of the critical oxygen concentrations corresponding to ignition and extinction on the diameter of a carbon particle was obtained analytically taking into account the internal reaction. It is shown that an increase in the pressure in the mixture leads to a decrease in the critical concentrations of oxygen.
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