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Chemistry for Sustainable Development

2020 year, number 6

Determination of the Nature of Carriers of Ash-Forming Elements in Coal from the Kaa-Khem Deposit

N. N. YANCHAT, L. KH. TAS-OOL
Tuvinian Institute for Exploration of Natural Resources, Siberian Branch of the Russian Academy of Sciences, Kyzyl, Russia
Keywords: coal, coal ash, ash carrier, ash-forming element
Pages: 593-598

Abstract

Statistical analysis of the material according to the composition of ash-forming elements in coal from the Kaa-Khem deposit ( n = 43) including the data previously obtained by other researchers was carried out. The study samples of coal have a low ash content on average (ash content Ad is 11.8 %), with a relatively high content of CaO (17.4 mass %) and Fe2O3 (16.6 mass %). Regression analysis of the data by means of the least-squares allowed us to reveal correlations between ash content and the content of elements. The dependences of the element’s contents in coal [E i ] and ash [E i ]A were estimated over a broad range of ash content values Ad (3-51 %). The types of diagrams for Si, Al, Ti, K, Na differ from those for Fe, Ca, Mg, S. It is demonstrated that the main carriers for Si, Al, Ti, K, Na in the studied coals are mineral inclusions of allothigenic origin. The authigenic mineral formations of coals contain mainly the carriers of Fe, Ca, Mg, S.

DOI: 10.15372/CSD2020270