CLAY MINERAL ASSEMBLAGES IN RECENT THERMAL ANOMALIES OF SOUTHERN KAMCHATKA
A.V. Sergeeva, D.K. Denisov, M.A. Nazarova
a:2:{s:4:"TEXT";s:153:"Institute of Volcanology and Seismology, Far Eastern Branch of the Russian Academy of Sciences, bul’var Piipa 9, Petropavlovsk-Kamchatsky, 683006, Russia";s:4:"TYPE";s:4:"text";}
Keywords: Thermal fields, hydrothermal clays, montmorillonite, kaolinite, alunite group minerals
Abstract
We consider the factors determining the mineral composition of hydrothermal clays in recent thermal anomalies of the Pauzhetka-Kambal’nyi-Koshelevskii region and Ebeko (Paramushir Island) and Mutnovskii Volcanoes. The composition of mineral assemblages is influenced by a number of interdependent factors: the type of discharge (steam-gas jets, heated grounds, and mud water pools), temperature, pH, and Eh of a thermal solution. Mineral assemblages including sulfur, opal, α-quartz, and alunite group minerals form on the heated grounds of the craters of active volcanoes (Ebeko and Mutnovskii). Mud water pools of the craters contain mainly sulfur, opal, and α-quartz. An assemblage of kaolinite, opal, alunite group minerals (in small amounts), and goethite forms in mud water pools with pH = 2-3 in the thermal fields of the Pauzhetka-Kambal’nyi-Koshelevskii region. An assemblage of newly formed kaolinite, smectite, pyrite, marcasite, and, sometimes, opal is specific to mud water pools with pH > 3.5-4.0 At pH > 5, smectite, pyrite, and opal are produced. In the thermal fields of the Pauzhetka-Kambal’nyi-Koshelevskii region, the walls of steam-gas jets that are often flooded with water and dry out are formed by kaolinite, smectite, opal, α-quartz, pyrite, marcasite, and goethite. The walls of steam-gas jets that are not flooded with water for a long time consist of kaolinite, opal, α-quartz, smectite (traces), alunite group minerals, pyrite, and marcasite in close amounts. The heated grounds of the thermal fields of the Pauzhetka-Kambal’nyi-Koshelevskii region are composed of kaolinite, alunite group minerals, opal, and goethite or an assemblage of kaolinite, smectite, opal, pyrite, and marcasite.
DOI: 10.15372/RGG2019090
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