Kinetic Parameters of Thermal Decomposition of Furazano-1,2,3,4-Tetrazine-1,3-Dioxide and Binary Solution Based on It
N.V. Murav'ev1, K. A. Monogarov1, V. E. Zarko2, P. I. Kalmykov3, A. N. Pivkina1
1Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow, 119991, Russia
2Voevodsky Institute of Chemical Kinetics and Combustion, Russian Academy of Sciences, Novosibirsk, 630090 Russia
3Altai Federal Research and Production Center, Biisk, 659322 Russia
Keywords: ФТДО, ДНП, дифференциальная сканирующая калориметрия, кинетические параметры, термораспад, FTDO, DNP, differential scanning calorimetry, kinetic parameters, thermal decomposition
Abstract
The kinetic parameters of thermal decomposition of furazano-1,2,3,4-tetrazine-1,3-dioxide (FTDO) and the FTDO/dinitrazapentane (DNP) (75/25%) system were experimentally investigated by differential scanning calorimetry. Kissinger kinetic analysis was performed using differential scanning calorimetry data obtained at heating rates of 0.1–5.0 K/min. It was found that the thermal decomposition of FTDO and the FTDO/DNP system occurs by a first-order reaction with an activation energy of 185 (FTDO) and 171 kJ/mol (FTDO/DNP).
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