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Atmospheric and Oceanic Optics

2019 year, number 2

Line broadening and line shift of water vapor and carbon oxide in the volume of aerogel nanopores

V.I. Starikov1,2
1Tomsk State University of Control Systems and Radioelectronics, 634050, 40 Lenina Prospect, Tomsk, Russia
2National Research Tomsk Polytechnic University, 30, Lenin Avenue, Tomsk, 634050, Russia
Keywords: водяной пар, окись углерода, нанопоры, уширение и сдвиг спектральных линий, water vapor, carbon oxide, nanopores, halfwidth and shift of spectral lines

Abstract

Calculations of line broadening and line shift of water vapor and carbon oxide confined in nanoporous media are presented. The collisions of free H2O (CO) molecules with physically adsorbed on the surface molecules are discussed. Changes in the rotational structure of levels in physically adsorbed molecules are taken into account. The comparison with the existing experimental data is performed.