MOLECULAR AND CRYSTAL STRUCTURE OF A CATIONIC DINITROSYL IRON COMPLEX WITH 1,3-DIMETHYLTHIOUREA
N. Yu. Shmatko, D. V. Korchagin, G. V. Shilov, N. A. Sanina, S. M. Aldoshin
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia
Keywords: оксид азота (NO), динитрозильные комплексы железа, 1,3-диметилтиомочевина, РСА, nitric oxide (NO), dinitrosyl iron complexes, 1,3-dimethylthiourea, single crystal X-ray diffraction
Abstract
A new dinitrosyl iron complex of the composition [Fe(SC(NHCH3)2)2(NO)2]Cl (I) is obtained by direct nitrosylation of ferrous sulfate and a hydrochloric acid solution of 1,3-dimethylthiourea. The characteristic features of the molecular and crystal structure of complex I is determined by single crystal X-ray diffraction analysis.
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