CRYSTALLOGENETIC ANALYSIS OF FLUORIDOBORATES AND ANALOGUES WITH THE CATIONIC М7-FRAMEWORK
V.V. Bakakin1, Yu.V. Seretkin2,3
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
3Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: катионные подрешетки, катионные каркасы, темплаты, ортобораты, фторидобораты, cation sublattices, cation frameworks, templates, orthoborates, fluoridoborates
Abstract
The organization principles of crystal structures of a series of fluoridoborates with large cations and their topological analogues are considered based on the current cation framework representations. Outer-framework anionic components are differentiated into leading (template) and subordinate with respect to their structure directing function.
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