CRYSTAL AND MOLECULAR STRUCTURE OF 1-(IODMETHYL)- AND 1-(IODPROPYL)SILATRANES
a:2:{s:4:"TYPE";s:4:"HTML";s:4:"TEXT";s:111:"I. V. Sterkhova1, V. I. Smirnov1, G. A. Kuznetsova1, E. A. Zel’bst2";}
1Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia
2Pedagogical Institute, Irkutsk, Russia
Keywords: 1-(иодметил)силатран, 1-(иодпропил)силатран, молекулярная структура, рентгеноструктурный анализ, 1-(iodmethyl)silatrane, 1-(iodpropyl)silatrane, molecular structure, single crystal X-ray diffraction analysis
Abstract
The crystal and molecular structures of 1-(iodmethyl)silatrane and 1-(iodpropyl)silatrane are determined by X-ray diffraction. The effect of the iodine heteroatom upon silatrane moieties of the molecules through one- and three-carbon chains is studied based on the geometric characteristics of the molecules and the analysis of their packings.
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