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Journal of Structural Chemistry

2015 year, number 4

IODOBISMUTHATE COMPLEX (Bu4N)3[Bi3I12]: CRYSTAL STRUCTURE OF A NEW POLYMORPH

S. A. Adonin1,2, E. V. Peresypkina1,2, M. N. Sokolov1,2, V. P. Fedin1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: висмут, иодидные комплексы, полиморфизм, кристаллическая структура, bismuth, iodide complexes, polymorphism, crystal structure

Abstract

The structure of a new polymorph of the trinuclear iodobismuthate complex TBA3[Bi3I12] (TBA = tetra-n-butylammonium) (1) synthesized by the reaction of BiI3+TBA-I in the presence of silver triflate is identified.