CRYSTAL STRUCTURE OF THE SEVEN-ELECTRON MOLYBDENUM CLUSTER [MO3S4(DPPE)3CL3]·3.5C4H8O2·0.5ET2O
P. A. Petrov1,2, G. A. Sosnin2, D. Yu. Naumov1, S. N. Konchenko1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: кластерные комплексы, молибден, сера, рентгеноструктурный анализ, cluster complexes, molybdenum, sulfur, single crystal X-ray diffraction study
Abstract
The seven-electron neutral cluster complex [Mo3S4(dppe)3Cl3] (dppe = Ph2PCH2CH2PPh2) is obtained by the reduction of the [Mo3S4(dppe)3Cl3]Cl cluster with gallium metal. The molecular and crystal structure of [Mo3S4(dppe)3Cl3]×3.5C4H8O2×0.5Et2O solvate is determined by single crystal XRD. The crystallographic data are as follows: monoclinic crystal symmetry, space group C2/c, a = 41.1775(16) Å, b = 17.7178(7) Å, c = 28.9609(9) Å, β = 110.363(1)°, V = 19808.7(13) Å3, Z = 8, dcalc = 1.384 g/cm3.
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