CRYSTAL STRUCTURE OF Cs2[Mo10S10O10(OH)10(H2O)4](C4H2S(PO2H)2)·21H2O
D. S. Ogienko1, A. I. Smolentsev1,2, S. N. Konchenko1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: полиядерные комплексы, молибден, сера, фосфор, гетероциклические соединения, супрамолекулярные соединения, кристаллическая структура, polynuclear complexes, molybdenum, sulfur, phosphorus, heterocyclic compounds, supramolecular compounds, crystal structure
Abstract
We have determined the crystal structure of a supramolecular compound Cs2[Mo10S10O10(OH)10(H2O)4](C4H2S(PO2H)2)×21H2O comprising quasi-one-dimensional chains consisting of alternating cyclical [Mo10S10O10(OH)10(H2O)4] clusters and C4H2S(PO2H2)2 acid residuals of thiophene-2,5-diphosphonic acid hydrogen bonded with each other.
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