STRUCTURE OF THE PRODUCT OF FREE-RADICAL SUBSTITUTION OF CHLORINE ATOMS IN IRON(II) CLATHROCHELATE WITH TWO ETHANOL FRAGMENTS
M. A. Vershinin1, A. B. Burdukov1, N. V. Pervukhina1, I. V. Eltsov2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk Natianal Research State University, Novosibirsk, Russia
Keywords: clathrochelates, iron(II), free-radical reactions, reactions of coordinated ligands, XRD, NMR
Abstract
The homolytic substitution of chlorine atoms afforded iron(II) clathrochelate bearing two ethanol fragments. The structure of the compound was determined by XRD in the crystalline state and by NMR in solution.
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