CRYSTAL STRUCTURE OF SILVER AND BARIUM NITROPALLADATES
A. V. Zadesenets1,2, M. Yu. Filippova2, I. A. Baidina1, S. V. Korenev1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia 2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: palladium, nitro complexes, silver
Abstract
New complex salts (barium and silver tetranitropalladates(II) Ba[Pd(NO2)4]×nH2O (n = 1, 3) and Ag2[Pd(NO2)4]) are synthesized. The compounds are characterized using elemental and X-ray diffraction analyses and IR spectroscopy. The salts crystallize in different space groups. The mutual orientation of nitro groups depending on the outer-sphere counter ion is examined.
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