EFFECT OF THE ANION NATURE ON THE STRUCTURE OF [RhL4Cl2]X (L=Py, γ– and β–picolines) COMPLEX SALTS
a:2:{s:4:"TEXT";s:118:"D. B. Vasil’chenko1,2, A. B. Venediktov1, I. A. Baidina1, S. V. Korenev1,2";s:4:"TYPE";s:4:"html";}
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: rhodium, pyridine, picoline, single-crystal X-ray diffraction
Abstract
An analysis is performed of the crystal structures of complex salts [RhL4Cl2]X (L=Py, γ- and β-picolines; X are different anions) in light of the effect induced by the nature of the anion X. It is shown that the intermolecular interactions between the anions play a key role in creating the general motif of the structure.
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