EFFECT OF THE ANION NATURE ON THE STRUCTURE OF [RhL4Cl2]X (L=Py, Оі– and ОІ–picolines) COMPLEX SALTS
D. B. Vasil’chenko1,2, A. B. Venediktov1, I. A. Baidina1, S. V. Korenev1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: rhodium, pyridine, picoline, single-crystal X-ray diffraction
Abstract
An analysis is performed of the crystal structures of complex salts [RhL4Cl2]X (L=Py, γ- and β-picolines; X are different anions) in light of the effect induced by the nature of the anion X. It is shown that the intermolecular interactions between the anions play a key role in creating the general motif of the structure.
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