Solid-Phase Nanoreactors for Alkyl Pyridine Oxidation
L. P. ABRAMOVA1, O. G. ALTSHULER1, N. V. MALYSHENKO1, E. V. OSTAPOVA1, L. A. SAPOZHNIKOVA1, G. YU. SHKURENKO1, V. YU. MALYSHEVA2, A. N. POPOVA2, G. N. ALTSHULER1
1Institute of Coal Chemistry and Material Science, Siberian Branch of the Russian Academy of Sciences, Pr. Sovetskiy 18, Kemerovo 650000 (Russia)
2Shared Instrumentation Centre of the Kemerovo Scientific Centre, Siberian Branch of the Russian Academy of Sciences, Ul. Rukavishnikova 21, Kemerovo 650025 (Russia)
Keywords: solid-phase nanoreactor, polymeric zirconium phosphonate, alkyl pyridines, oxidation
Abstract
Principal possibility to use polymeric phosphonate and dioxide of zirconium containing nanoparticles of palladium, silver and platinum as solid-phase nanoreactors for the catalytic oxidation of alkyl pyridines of coal-tar resin (β-picoline, γ-picoline, 2,6-lutidine) to pyridine carboxylic (nicotinic, isonicotinic and 2,6-pyridine carboxylic) acids - precursors of antituberculous preparations - was demonstrated.
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