CRYSTAL AND MOLECULAR STRUCTURE OF BENZOAZA-12-CROWN-4 HYDROCHLORIDE
V. N. Glushko1, N. Yu. Sadovskaya1, L. I. Blokhina1, I. V. Anan'ev2
1State Scientific Research Institute of Chemical Reagents and High Purity Chemical Substances, Moscow, Russia
2Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
Keywords: рентгеноструктурный анализ, краун-эфиры, бензоаза-12-краун-4, X-ray crystallographic analysis, crown ethers, benzoaza-12-crown-4
Subsection: STRUCTURE OF BIOLOGICALLY ACTIVE SYSTEMS
Abstract
The X-ray crystallographic analysis of benzoaza-12-crown-4 hydrochloride crystals is performed for the first time: space group
Р1,
а = 7.7497(4) Å,
b = 9.2224(5) Å,
c = 10.2395(5) Å, α = 99.3965(10)°, β = 101.8387(11)°, γ = 112.6470(10)°,
V = 636,81(6) Å
3,
Z = 2, ρ
calc = 1.355 g/cm
3. The conformation of the 12-membered ring of the molecule is determined.
DOI: 10.1134/S0022476615010205
|
