CRYSTAL STRUCTURE OF THE COORDINATION POLYMER [Cu 2( S-mal) 2(bpy) 2(H 2O)]·2.5H 2O
M. S. Zavakhina1,2, D. G. Samsonenko1,2, V. P. Fedin1,2
1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk National Research State University, Novosibirsk, Russia
Keywords: медь, координационные полимеры, металл-органические каркасы, хиральные комплексы, яблочная кислота, copper, coordination polymers, metal-organic frameworks, chiral complexes, malic acid
Abstract
In the interaction of basic copper carbonate with optically pure malic acid and 4,4'-bipyridine [Cu
2(
S-mal)
2(bpy)
2(H
2O)]×2.5H
2O (1) is obtained. The structure of the metal-organic coordination polymer is unique for this class of compounds, which is established by the single crystal X-ray diffraction analysis using synchrotron radiation.
DOI: 10.1134/S0022476615010151
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