CRYSTAL STRUCTURE OF [Cp3*Ir3S2]Cl{(H2O)(HSO4)(H2SO4)}·CHCl3
P. A. Abramov1,2, A. V. Virovets1, M. N. Sokolov1,2
1Nikolaev Institute of Inorganic chemistry Siberian Branch of the Russian Academy of Science, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
Keywords: iridium, sulfide, supramolecular associate, X-ray structural analysis
Subsection: SELF-ASSEMBLY AND SUPRAMOLECULAR ORGANIZATION OF COORDINATION COMPOUNDS
Abstract
Reaction of [Cp*IrCl2]2 with (Me3Si)2S in the presence of moisture leads to the formation of a triangular cluster [Cp3*Ir3S2]2+, which was isolated and characterized as supramolecular adduct [Cp3*Ir3S2]Cl{(H2O)(HSO4)(H2SO4)}·CHCl3 (1).
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