CRYSTAL AND MOLECULAR STRUCTURE OF DICESIUM BIS(MALONATO)-DI-μ-SULPHIDO-BIS[OXOMOLYBDATE(V)] DIHYDRATE: Cs2[Mo2O2S2(MALONATE)2(H2O)2]·2H2O
Fadel M. Abou1, N. Watfa1,2, S. Floquet1, J. Marrot1, M. Awada1, A. Hijazi2, D. Naoufal2, E. Cadot1
1Institut Lavoisier de Versailles, Versailles Cedex, France
2Lebanese University, Hadath, Beirut, Lebanon
Keywords: chalcogenide, thiometalate, polyoxometalate, molybdenum, sulfur
Subsection: SELF-ASSEMBLY AND SUPRAMOLECULAR ORGANIZATION OF COORDINATION COMPOUNDS
Abstract
The compound Cs2[Mo2O2S2(C3H2O4)2(H2O)2]×2H2O has been synthetized and isolated as single crystals. It crystallizes in the Pnma space group and the structural analysis reveals that all the components are held together to build a 3D compact layered network, evidencing that {Mo2O2S2}–based molecular complexes can be used as building units for the elaboration of metal organic frameworks materials.
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