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Journal of Mining Sciences

2014 year, number 4

Up-to-Date Approaches to Adsorption of Fatty-Acid Collecting Agents at Apatite and Shtaffelite Ore Minerals

V. A. CHANTURIA1, YU. E. BRYLYAKOV2, E. V. KOPORULINA1, M. V. RYAZANTSEVA1, I. ZH. BUNIN1, I. A. KHABAROVA1, A. N. KRASNOV1
1Institute of Problems of Comprehensive Exploitation of Mineral Resources Russian Academy of Sciences, Kryukovskii tupik 4, Moscow, 111020 Russia
2EvroKhim Research Center LLC, ul. Fersmana 24, Apatity, 184209 Russia
Keywords: apatite and shtaffelite ore minerals, apatite, shtaffelite, calcite, flotation agents, surface, adsorption, analytical electron microscopy, high resolution microscopy, IR spectroscopy

Abstract

The morphology and spread of micro- and nano-formations on surface of apatite and shtaffelite ore minerals (apatite, shtaffelite and calcite) due to adsorption of fatty-acid collecting agents have been studied using the methods of optical, laser confocal scanning, analytical electron and atomic force microscopy. The Fourier-transform IR spectroscopy has shown that fatty-acid collecting agents are adsorbed on surface of apatite, shtaffelite and calcite in a mixed ion-molecule form; the ion form of attachment prevails for calcite.