CRYSTAL AND MOLECULAR STRUCTURE OF 1–(3–AMMONIOPROPYL)SILATRANE CHLORIDE
a:2:{s:4:"TEXT";s:173:"M. G. Voronkov1, È. A. Zel’bst2, V. S. Fundamensky3, V. V. Gurzhiy3, Yu. I. Bolgova1, O. M. Trofimova1";s:4:"TYPE";s:4:"html";}
1Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia
2East Siberian State Academy of Education, Irkutsk, Russia
3Saint-Petersburg State Institute of Technology, Saint-Petersburg, Russia
Keywords: 1-(3-ammoniopropyl)silatrane chloride, molecular structure, single crystal X-ray diffraction study
Abstract
By single crystal X-ray diffraction the crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride (I) is determined. One of three cations in the asymmetric unit of the crystal of I differs from the other two by the length of the coordination N ® Si bond. The opposite electronic effects in two geometrically similar cations are transferred inductively through a three-carbon chain.
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