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2014 year, number 2

CRYSTAL STRUCTURE OF [Co(NH3)5Cl]2(W10O32)·4Н2O

N. V. Kuratieva1,2, S. P. Khranenko1, S. A. Gromilov1,2
a:2:{s:4:"TEXT";s:263:"1Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Scientific and Educational Complex «Nanosystems and Advanced Materials», Novosibirsk, Russia";s:4:"TYPE";s:4:"html";}
Keywords: decatungstate, cobalt, complex salt, crystal chemistry, single crystal X-ray diffraction study

Abstract

By single crystal X-ray diffraction the crystal structure of the complex salt [Co(NH3)5Cl]2(W10O32)×4H2O is determined and the IR spectrum is interpreted. The crystal chemical analysis of the structure of complex cations and decatungstate anions and their packing in the structure is performed.