Publishing House SB RAS:

Publishing House SB RAS:

Address of the Publishing House SB RAS:
Morskoy pr. 2, 630090 Novosibirsk, Russia



Advanced Search

Russian Geology and Geophysics

2013 year, number 8

BIOMARKERS AND ADAMANTANES IN CRUDE OILS FROM CENOMANIAN DEPOSITS OF NORTHERN WEST SIBERIA

V.A. Kashirtsev, I.I. Nesterov, V.N. Melenevskii, E.A. Fursenko, M.O. Kozakov, A.V. Lavrenov
Keywords: Crude oil, geochemistry, hydrocarbon biomarkers, adamantanes, Cenomanian, West Siberia

Abstract

Chromato-mass-spectrometric studies made it possible to identify a wide spectrum of hydrocarbon biomarkers in crude oils from Cenomanian pools of northern West Siberia (Russkoe, Pangodinskoe, Van-Eganskoe, Severo-Komsomol’skoe). The distribution pattern of the main hydrocarbon components ( n -alkanes, acyclic isoprenanes, steranes, terpanes) shows that most of the oils underwent intense microbial oxidation. We have established high concentrations of 25-norhopanes typical of high-degree degradation; demethylated hopanes are also revealed in “alkane” crude oils. Among low-molecular chemofossils, biand tricyclic monoand sesquiterpanes have been recognized, whose precursors are usually biomolecules synthesized by plants. Unsaturated precursors of monoand sesquiterpanes might have been the starting material for thermocatalytical synthesis of framework adamantanoid structures, whose high concentrations have been found in alkane-free crude oils.