Structure of new carbonyl cluster complexes with the [Fe4(μ4-Q)(μ4-AsCH3)(CO)11] core
D. A. Bashirov1,2, N. V. Kuratieva1,2, A. I. Smolentsev1, S. N. Konchenko1,2
1A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
2Novosibirsk State University
Keywords: carbonyl cluster, iron, synthesis, crystal structure
Abstract
By X‑ray diffraction study the structure of two new carbonyl cluster complexes of the composition [Fe4(μ4-Q)(μ4-AsMe)(CO)11], where Q = Se or Te, is determined. The structures are molecular, and the selenium-containing cluster complex crystallizes in the form of a solvate with toluene.
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