CRYSTAL STRUCTURE OF LAYERED METAL-ORGANIC COORDINATION POLYMERS BASED ON TRINUCLEAR ZINC CARBOXYLATES: [Zn3(DMA)2(bpdc)3]·3DMA AND [Zn3(im)2(bdc)3]·1.5H2O
S. B. Aliev1, D. G. Samsonenko1,2, V. P. Fedin1,2
1A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk
cluster@niic.nsc.ru
2Novosibirsk State University
Keywords: zinc, crystal structure, coordination polymers, metal-organic frameworks, carboxylic acids
Abstract
New layered metal-organic coordination polymers [Zn3(bpdc)3(DMA)2]·3DMA (1) (H2bpdc = 4,4′-bi-phenyldicaboxylic acid, DMA = N,N' -dimethylacetamide) and [Zn3(bdc) 3(im)2]·1.5H2O (2) (H2bdc = tere-phtalic acid, im = imidazole) are synthesized and characterized by X-ray crystallography.
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