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Chemistry for Sustainable Development

2011 year, number 2

Synthesizing Betulin Vinyl Ethers via Direct Vinylation by Acetylene in Superbasic KОН/DMSO Medium

A. V. ORLOV1, N. G. KOMISSAROVA2 and O. V. SHITIKOVA2
1 Ufa State Academy of Economics and Services
2 Institute of Organic Chemistry, Ufa Scientific Centre of the Russian Academy of Sciences
ngkom@anrb.ru
Keywords: betulin, acetylene, vinyl esters, superbasic medium
Pages: 213-216

Abstract

Basing on betulin vinylation by acetylene in superbasic medium KOH/DMSO, mono- and divinyl esters of betulin, valuable monomers and intermediates for the synthesis of polymers and biologically active compounds were obtained.