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Chemistry for Sustainable Development

2011 year, number 2

A Single-Stage Catalytic Process for Obtaining Dimethyl Ether from Synthesis Gas

N. I. KOSOVA and L. N. KURINA
Tomsk State University
kosova@mail.tsu.ru
Keywords: synthesis gas, CuO/ZnO/Al2О3 catalyst, dimethyl ether
Pages: 201-205

Abstract

Obtaining dimethyl ether from synthesis gas with the use of a two-layer catalyst was studied. An optimum level-by-level loading was determined for two catalytic systems such as methanol production catalyst Katalco-58 and methanol dehydration catalyst γ-Al2O3 It was demonstrated that increasing the temperature and contact time results in increasing the CO conversion level and the yield of dimethyl ether, whereas their maximum values are attained at a pressure of 3 MPa. The optimum process conditions are: Т = 280 °С, Р = 3 MPa, Н2/СО = 2, the contact time 6 s.