CRYSTAL STRUCTURES OF TWO SOLVATES OF MOLYBDENUM OCTAHEDRAL CLUSTERS: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN AND (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2
M. N. Sokolov, М. А. Mikhailov, P. A. Abramov, V. P. Fedin
Keywords: clusters, molybdenum, chlorides, p-toluenesulfonates, crystal structures, solvates
Pages: 200-204
Abstract
Crystal structures of two solvates (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN (1) and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2 (2) are determined. Both compounds contain cluster [Mo6Cl8(O3SC6H4CH3)6]2- anions. Molybdenum atoms are coordinated with monodentate carboxylate ligands (Mo-O 2.101(3)-2.110(3) Å in 1; 2.088(7)-2.109(2) Å in 2).
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