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Russian Geology and Geophysics

2009 year, number 12

THE COEFFICIENTS OF HETEROVALENT NASI-CAAL INTERDIFFUSION IN PLAGIOCLASES

V.N. Korolyuk, G.G. Lepezin
Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, 3 prosp. Akad. Koptyuga, Novosibirsk, 630090, Russia
Keywords: Plagioclase, diffusion coefficient, thermal history of rocks
Pages: 1146-1152

Abstract

Literature data on the coefficients of heterovalent NaSi-CaAl interdiffusion in plagioclases are analyzed. It is shown that activation energy and frequency factor decrease as the partial pressure of water and plagioclase basicity increase. A general expression has been derived for the interdiffusion coefficients of albite and anorthite asa function of the plagioclase composition (N Pl ), temperature T (K), and water pressure (kbar):
D [см2/c] = exp {13.14 - 0.354NPl + 40.72/(1 + P2H2O) - (116095 - 1037NPl + 139732/(1 + P2H2O))/RT }