Publishing House SB RAS:

Publishing House SB RAS:

Address of the Publishing House SB RAS:
Morskoy pr. 2, 630090 Novosibirsk, Russia



Advanced Search

Chemistry for Sustainable Development

2007 year, number 5

Acid-Catalysed Isomerization of Caryophyllen Oxide in the Presence of SiO2 and Al2O3 Impregnated with Sulphuric Acid

E. P. Romanenko, A. V. Tkachev
Pages: 581-594

Abstract

Catalytic activity of silica gel and aluminium oxide impregnated with sulphuric acid (H+-SiO2 and H+-Al2O3, respectively) in the reaction of acid-catalysed isomerization of caryophyllen oxide was investigated. It was established that the activity of H+-SiO2 is much higher than that of H+-Al2O3 and is comparable with the activity of concentrated sulphuric acid. For silica gel H+-SiO2, the dependence between the catalytic activity and the size of silica gel particles was revealed.